Rare earth elements in sediments of the Vigo Ria,NW Iberian Peninsula     

Ricardo Prego  Miguel Caetano  Carlos Vale  Judith Marmolejo-Rodríguez 《Continental Shelf Research》2009

The abundance and distribution of rare earth elements (REE) and their signatures in the Vigo Ria were studied from 50 samples of surface sediments and related to the geological formation in its watershed. The total amount of REE in the Ria is heterogeneous. It ranges from 220 mg kg⁻¹ in the southern middle Ria margin in the vicinity of the Galiñeiro geological shore complex, which contains REE-enriched minerals, to 2 mg kg⁻¹ near the Ria mouth due to dilution with high levels of carbonated biogenic particles (31% of Ca). Rare earth elements of the Ria sediments are considerably enriched in light-REE relative to heavy-REE (a LREE/HREE ratio of 9.7±1.6) and also show a slightly negative Eu-anomaly. Low European shale normalised REE patterns were distinguished in the innermost sediments of Vigo Ria, but were not correlated with Al. This suggests a minor contribution of REE from upstream freshwater inputs to the sediments in the middle Vigo Ria zone. Normalised REE ratios in the middle Ria imply that fine particles enriched in REE may be exported from the Ria to shelf mud patches and REE can be useful as sediment tracers of Ria input on the shelf.  相似文献   

GIS in the K-12 Curriculum: A Cautionary Note   总被引：7，自引：0，他引：7  

Judith W. Meyer  Jon Butterick  Michael Olkin  George Zack 《The Professional geographer》1999,51(4):571-578

Two qualitative case studies, one focusing on K-12 teachers and the other on middle school students, explore key factors associated with using Geographic Information Systems in the classroom. In both studies, access to appropriate hardware is a critical barrier. Time is another critical barrier—time to learn the GIS software and time in the curriculum to incorporate GIS as a learning experience. In both case studies, learning the technology at the expense of learning spatial analysis was a danger, suggesting the need for conscious focus on the goal of using GIS to learn how to “do geography.”  相似文献   

The geochemistry of sulphur in a mixed allogenic–autogenic karst catchment,Castleton, Derbyshire,UK     

Simon H. Bottrell  Neil Webber    John Gunn  Stephen R. H. Worthington 《地球表面变化过程与地形》2000,25(2):155-165

Analyses are presented of anion chemistry and sulphur isotopic compositions of sulphate in sinking streams and groundwaters in a mixed allogenic–autogenic karst catchment. Using the sulphur isotopic data, sources of sulphate from agriculture and the effects of sulphate reduction arising from slurry application can be distinguished from natural rock weathering sources. Within the aquifer, sulphate in known autogenic waters has isotopic compositions distinct from allogenic waters, the autogenic waters being dominated by sulphate from rainfall and rock weathering in these low agricultural intensity catchments. On this basis, water rising at low flow from Whirlpool Rising, Speedwell Cavern, has been identified as dominantly autogenic. Groundwater flow between the sinks and risings in Speedwell Cavern is believed to be along conduits following mineralized faults (rakes). During transit SO42−/Cl− in the water increases. Isotopic mass balance shows that this must be due to addition of sulphate from the oxidation of ore minerals by groundwater. Mass balance considerations show that the present rate of sulphide oxidation must be the result of enhancement by lead mining operations on the rakes. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   

Use of Sonication for Enhanced Sampling of Attached Microbes from Groundwater Systems     

Murray Close  Phil Abraham  Judith Webber  Eliza Cowey  Bronwyn Humphries  Graham Fenwick  Simon Howard  Kimberly Huynh  Travis Grace  Pierre-Yves Dupont  Louise Weaver 《Ground water》2020,58(6):901-912

The vast majority of microorganisms in aquifers live as biofilms on sediment surfaces, which presents significant challenges for sampling as only the suspended microbes will be sampled through normal pumping. The use of a down-well low frequency sonicator has been suggested as a method of detaching microbes from the biofilm and allowing rapid sampling of this community. We developed a portable, easy to use, low-frequency electric sonicator and evaluated its performance for a range of well depths (tested up to 42 m below ground level) and casing types. Three sonicators were characterized in laboratory experiments using a 1 m long tank filled with pea gravel. These included a commercially available pneumatic sonicator, a rotating flexible shaft sonicator, and the prototype electric sonicator. The electric sonicator detached between 56 and 74% of microbes grown on gravel-containing biobags at distances ranging between 2 and 50 cm from the sonicator. The field testing comprises of a total of 55 sampling events from 48 wells located in 4 regions throughout New Zealand. Pre- and post-sonication samples showed an average 33 times increase in bacterial counts. Microbial sequence data showed that the same classes are present in pre- and post-sonicated samples and only slight differences were seen in the proportions present. The sampling process was rapid and the significant increases in bacterial counts mean that microbial samples can be quickly obtained from wells, which permits more detailed analysis than previously possible.  相似文献   

Bed material transport estimated from the virtual velocity of sediment     

Judith K. Haschenburger  Michael Church 《地球表面变化过程与地形》1998,23(9):791-808

This study evaluates the possibility of determining bed material transport using the virtual rate of travel of individual particles, dimensions of the active layer of the streambed, and porosity and density of streambed material. Magnetically tagged stones and scour indicators were employed in Carnation Creek, British Columbia, to quantify transport rates. Observations cover flows up to 36 m³ s⁻¹ (τ* = 0·081). Transport rates, ranging from 0·090 to 9·7 kg s⁻¹ (0·12–13·2 m³ h⁻¹), display a relatively sensitive trend with maximum stream power, as expected. Error analysis indicates that uncertainty in virtual velocity covers the majority of sample variance. An evaluation of the two measurement techniques used to delineate active layer dimensions, magnetically tagged stones and scour indicators, indicates that they yield comparable depths, widths and transport rates over the range of flows observed. Issues for further study are discussed. © 1998 John Wiley & Sons, Ltd.  相似文献   

Chemical Procedures for Rhenium Extraction from Geological Samples: Optimising the Anion Resin Bead Clean‐up Step     

Gang Yang  Aaron Zimmerman  Nicole C. Hurtig  Svetoslav V. Georgiev  Vineet Goswami  Judith L. Hannah  Holly J. Stein 《Geostandards and Geoanalytical Research》2020,44(2):231-242

Rhenium–osmium geochronometry for samples with low Re and complex matrices requires improved Re extraction methods. Here, we investigate plausible controls on efficiency and efficacy of Re extraction during our anion resin bead purification. Four different protocols are compared, each isolating a single variable to test. Rhenium concentrations for solutions at each step of each protocol document differences in chemical recovery/yield. The negative‐thermal ionisation mass spectrometry (N‐TIMS) signal intensity serves as a proxy for Re yield and purity. These data document correlations between the N‐TIMS signal intensity and (a) the duration of anion resin bead conditioning prior to loading with Re‐bearing solution, and (b) both duration and strength of nitric acid used during rinsing of the Re‐loaded anion resin bead. The optimal protocol improved Re signal intensity around fourteen times compared with our current Re extraction protocol, an aggregate of 2.4 times improvement in chemical recovery (yield) and 5.8 times improvement in emission efficiency (purity). Repeated N‐TIMS isotopic measurements on our in‐house Re standard solution (1407) verify that our optimal protocol‐3 does not fractionate Re isotopes. The improved anion resin bead method considerably lowers the Re detection limit and allows Re‐Os isotopic analysis of picogram‐level Re hosted in geological samples with complex matrices.  相似文献   

Gentrifier,by John Joe Schlichtman,Jason Patch,and Marc Lamont Hill     

Judith R. Halasz 《Urban geography》2019,40(1):160-162

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Ecometrics and the paleoecological implications of Pleistocene faunas from the western coastal plains of the Cape Floristic Region,South Africa     

J. Tyler Faith  David R. Braun  Benjamin Davies  Larisa R. G. DeSantis  Matthew J. Douglass  Irene Esteban  Vincent Hare  Naomi E. Levin  Julie Luyt  Robyn Pickering  Mitchell J. Power  Judith Sealy  Deano Stynder 《第四纪科学杂志》2020,35(8):1007-1020

The Pleistocene ungulate communities from the western coastal plains of South Africa's Cape Floristic Region (CFR) are diverse and dominated by grazers, in contrast to the region's Holocene and historical faunas, which are relatively species-poor and dominated by small-bodied browsers and mixed feeders. An expansion of grassy habitats is clearly implied by the Pleistocene faunas, but the presence of ruminant grazers that cannot survive the summer dry season typical of the region today suggests other important paleoecological changes. Here we use dental ecometrics to explore the paleoecological implications of the region's Pleistocene faunas. We show that the dental traits (hypsodonty and occlusal topography) of the ungulates that occurred historically in the CFR track annual and summer aridity, and we use these relationships to reconstruct past aridity. Our results indicate that the Pleistocene faunas signal paleoenvironments that were on average less arid than today, including during the summer, consistent with other lines of evidence that suggest a higher water table and expansion of well-watered habitats. Greater water availability can be explained by lower temperature and reduced evapotranspiration during cooler phases of the Pleistocene, probably coupled with enhanced groundwater recharge due to increased winter precipitation.  相似文献   

Assessment of present and future nitrogen loads, water quality, and seagrass (Thalassia testudinum) depth distribution in Lemon Bay, Florida     

David A. Tomasko  Denise L. Bristol  Judith A. Ott 《Estuaries and Coasts》2001,24(6):926-938

Nitrogen loads into Lemon Bay, Florida were modeled to have increased ca. 59% between pre-development (i.e., 1850) estimates (5.3 kg TN ha⁻¹ yr⁻¹. and estimates for the year 1995 (8.4 kg TN ha⁻¹ yr⁻¹). By the year 2010, nitrogen loads are predicted to increase an additional 45% or 58%, depending upon progress being made toward replacing older septic tank systems with centralized sewerage (nitrogen loads of 12.2 and 13.3 kg TN ha⁻¹ yr⁻¹, respectively). Using 1995 estimates, nonpoint sources (stormwater runoff) are throught to be responsible for ca. 76% of the annual nitrogen load, followed by septic tank systems (14%), rainfall (10%), and an insignificant load from baseflow. Based on an empirically-derived nitrogen load:chlorophylla relationship developed for a portion of nearby Tampa Bay, a 45% increase in nitrogen loads into Lemon Bay could result in a 29% increase in annual average chlorophylla concentrations. Using the estimate of a 29% increase in future chlorophylla concentrations, an empirically-derived optical model for Lemon Bay suggests that light attenuation coefficients in the bay would increase ca. 9%, and the average depth limit ofThalassia testudinum in Lemon Bay would decrease by ca. 24%.  相似文献   

Ageing research in Australia: reflecting on Graeme Hugo’s four decades of contribution     

Debbie Faulkner  Helen Barrie Feist  Judith Lewis 《The Australian geographer》2016,47(4):399-415

ABSTRACT

Globally, population ageing is one of the most pressing social and policy issues faced today. Over the next two decades, Australian society will face dramatic increases in the proportion of the population aged 65 years and over, as the baby boomers move into older age and fertility levels remain low. Yet population ageing is not a surprising or new trend—demographic changes in the age profile of a population tend to occur incrementally rather than suddenly. As a demographer and geographer, Graeme Hugo drew attention to this trend in Australia’s population more than three decades ago. Throughout Graeme Hugo’s vast breadth of work over the past 40 years, there has been a consistent thread of demographic analysis and academic thought associated with the ageing of Australia’s population. This paper focuses on Hugo’s contributions to academic thought and policy on Australia’s ageing population and the challenges associated with this for both service delivery and health policy as Australian society moves into an unprecedented era of population ageing.  相似文献